Acid-Induced Degradation of Sand Rock in Yungang Grottoes

YAN Shao-jun, TAN Song-e, LIU Jun-hong, ZHAO Yu-bo

Journal of Changjiang River Scientific Research Institute ›› 2013, Vol. 30 ›› Issue (9) : 64-68.

PDF(1942 KB)
PDF(1942 KB)
Journal of Changjiang River Scientific Research Institute ›› 2013, Vol. 30 ›› Issue (9) : 64-68.
ROCK-SOIL ENGINEERING

Acid-Induced Degradation of Sand Rock in Yungang Grottoes

  • YAN Shao-jun, TAN Song-e, LIU Jun-hong, ZHAO Yu-bo
Author information +
History +

Abstract

Datong city, where the Yungang Grottoes is located in, is an important coal producing and coal chemical industry base in China. The SO2 concentration in the Grottoes area exceeds the standard because of air pollution. The feldspar and calcareous cement, which are the main mineral compositions of the sandstone in Yungang Grottoes, are very sensitive to acid. A sulfuric acid solution and sand rock reaction test was carried out to simulate the rock degradation. To study the mechanism of Grottoes rock deterioration caused by sulfuric acid, three steps are included in the test: immersing the sandstone samples into static sulfuric acid solution of different pH values; measuring the solution’s pH value, the mass and wave velocity of sandstone samples during the tests; and comparing the changes of samples’ compressive strength and physical structure before and after the test. Test results show that the sulfuric acid poses very quick degradation on calcium cementation sandstones, and it mainly focuses on damaging the calcium cement. As the reaction cycle increases, the wave velocity declined markedly. Degradation by sulfuric acid is extremely serious on the surface layer of sandstone samples. With the loss of calcareous cement, the rock strength reduces significantly.

Key words

Yungang Grottoes / sandstone / sulfuric acid / degradation

Cite this article

Download Citations
YAN Shao-jun, TAN Song-e, LIU Jun-hong, ZHAO Yu-bo. Acid-Induced Degradation of Sand Rock in Yungang Grottoes[J]. Journal of Changjiang River Scientific Research Institute. 2013, 30(9): 64-68

References

[1] 李 海. 大气污染对云冈石窟的风化侵蚀及防护对策[J] . 雁北师范学院学报, 2003, 19(5):60-63. (LI Hai. Air Pollution on the Weathering and Erosion Protection Measures of Yungang Grottoes[J] . Journal of Yanbei Normal University, 2003, 19(5):60-63.(in Chinese)
[2] 马在平, 黄继忠, 张 洪. 云冈石窟砂岩中碳酸盐胶结物化学风化及相关文物病害研究[J] .中国岩溶, 2005, 24(1):71-76.(MA Zai-ping, HUANG Ji-zhong, ZHANG Hong. Weathering of Carbonate Cement in Sandstone and the Related Cultural Relic Diseases in Yungang Grottoes[J] . Carsologica Sinica, 2005, 24(1):71-76. (in Chinese)
[3] 黄继忠.云冈石窟主要病害及治理[J] .雁北师范学院学报, 2003,19(5):57-59.(HUANG Ji-zhong. Major Diseases and Treatment in Yungang Grottoes[J] . Journal of Yanbei Normal University, 2003, 19(5):57-59.(in Chinese)
[4] 崔 强, 冯夏庭, 薛 强, 等.化学腐蚀下砂岩孔隙结构变化的机制研究[J] .岩石力学与工程学报, 2008, 27(6): 1209-1218.(CUI Qiang, FENG Xia-ting, XUE Qiang, et al. Study on Mechanism of Porosity Structure Change of Sandstone under Chemical Corrosion[J] . Chinese Journal of Rock Mechanics and Engineering, 2008,27(6):1209-1218.(in Chinese)
[5] 杨振峰, 缪林昌.粉砂质泥岩的强度衰减与环境效应试验研究[J] .岩石力学与工程学报, 2007, 26(12): 2576-2583.(YANG Zhen-feng, MIU Lin-chang. Experimental Study on Silty Mudstone Strength Attenuation and Environmental Effect[J] . Chinese Journal of Rock Mechanics and Engineering, 2007, 26(12): 2576-2583.(in Chinese)
[6] 谭卓英, 柴红保, 刘文静,等. 岩石在酸化环境下的强度损伤及其静态加速模拟[J] . 岩石力学与工程学报, 2005,24(14):2439-2450.(TAN Zhuo-ying, CHAI Hong-bao, LIU Wen-jing, et al. Rock Strength Deterioration under Acidified Conditions and Its Static Accelerated Simulation[J] . Chinese Journal of Rock Mechanics and Engineering, 2005, 24(14): 2439-2450.(in Chinese)
[7] 乔丽苹, 刘 建, 冯夏庭. 砂岩水物理化学损伤机制研究[J] . 岩石力学与工程学报,2007,26(10):2117-2124.(QIAO Li-ping, LIU Jian, FENG Xia-ting. Study on Damage Mechanism of Sandstone under Hydro-Physico-Chemical Effects[J] . Chinese Journal of Rock Mechanics and Engineering, 2007, 26(10): 2117-2124.(in Chinese)
[8] 李 宁,朱运明,张 平,等.酸性环境中钙质胶结砂岩的化学损伤模型[J] .岩土工程学报, 2003, 25(4):395-399.(LI Ning, ZHU Yun-ming, ZHANG Ping, et al. A Chemical Damage Model of Sandstone in Acid Environment [J] . Chinese Journal of Geotechnical Engineering, 2003, 25(4): 395-399.(in Chinese)
[9] 刘 杰, 李建林, 张玉灯, 等. 宜昌砂岩不同pH值酸性溶液浸泡时间比尺及强度模型研究[J] . 岩石力学与工程学报, 2010, 29(11):2319-2328.(LIU Jie, LI Jian-lin, ZHANG Yu-deng, et al. Study of Time Scale and Strength Model of Yichang Sandstone under Different pH Values of Acidic Solution Immersion[J] . Chinese Journal of Geotechnical Engineering, 2010, 29(11):2319-2328.(in Chinese)
[10] 李汶国,张晓鹏,钟玉梅.长石砂岩次生溶孔的形成机理[J] .石油与天然气地质,2005,26(2):220-224.(LI Wen-guo, ZHANG Xiao-peng, ZHONG Yu-mei. Formation Mechanism of Secondary Dissolved Pores in Arcose [J] . Oil & Gas Geology, 2005,26(2):220-224.(in Chinese)
[11] 丁梧秀, 冯夏庭. 渗透环境下化学腐蚀裂隙岩石破坏过程的CT试验研究[J] . 岩石力学与工程学报, 2008, 27(9):1865-1873.(DING Wu-xiu, FENG Xia-ting. CT Experimental Research of Fractured Rock Failure Process under Chemical Corrosion and Permeation[J] . Chinese Journal of Rock Mechanics and Engineering, 2008, 27(9):1865-1873.(in Chinese)
PDF(1942 KB)

Accesses

Citation

Detail

Sections
Recommended

/