含氯消毒剂的大规模使用势必导致其残留物通过降雨径流等途径进入天然水体造成余氯污染。为探究余氯在湖泊中的时空分布规律,采用Infoworks ICM仿真平台建立南湖水动力-水质模型,分析不同加氯周期和降雨条件下南湖余氯浓度时空变化。结果表明:① 余氯单次排入时,首先于近岸水体形成高余氯浓度区,由湖岸向湖心扩散且浓度递减;余氯输入结束时,浓度达到峰值1.25 mg/L,随后逐步衰减,余氯衰减趋向呈水域中心指向边界;全过程历时约14 h。② 周期性排入的影响主要体现在新周期余氯衰减速率有所减小,衰减历时增加且余氯浓度峰值有所增加,3个周期峰值分别为1.25、1.58、1.89 mg/L,历时分别为14、15.7、17.1 h。③ 降雨影响下,余氯污染范围增大,向湖心深入;历时更长,约20 h,浓度峰值增加,达到7 mg/L。
Abstract
The widespread use of chlorine-containing disinfectants inevitably leads to chlorine pollution as residues enter natural water bodies through rainfall runoff. To investigate the temporal and spatial distribution of chlorine in lakes, a hydrodynamic-water quality model of Nanhu Lake was established using the Infoworks ICM simulation platform. The model was used to analyze the temporal and spatial variation of chlorine concentration in Nanhu Lake under different chlorine discharge cycles and rainfall conditions. The results indicated that: 1) During a single discharge, a high concentration zone of chlorine was initially formed in the nearshore water body. The chlorine diffused from the lakeshore to the lake center, where the concentration decreased. At the end of chlorine discharge, the concentration reached a peak value of 1.25 mg/L and gradually decreased, with chlorine concentration attenuating from the water center towards the boundary. This process lasted approximately 14 hours. 2) The influence of periodic inflow is mainly reflected in the decrease of chlorine decay rate in the new cycle. The decay duration increased, and the peak value of chlorine concentration also increased. The peak values of chlorine concentration in three cycles were 1.25 mg/L, 1.58 mg/L, and 1.89 mg/L, respectively, with decay durations being 14 hours, 15.7 hours, and 17.1 hours, respectively. 3) Under the influence of rainfall, the range and depth of chlorine pollution expanded towards the lake center, and the pollution duration increased to approximately 20 hours. The peak concentration of chlorine also increased, reaching up to 7 mg/L.
关键词
水环境 /
余氯 /
时空分布 /
含氯消毒剂 /
Infoworks ICM /
南湖
Key words
water environment /
residual chlorine /
spatial and temporal distribution /
chlorine-containing disinfectant /
Infoworks ICM /
Nanhu Lake
{{custom_sec.title}}
{{custom_sec.title}}
{{custom_sec.content}}
参考文献
[1] 叶利兰, 甘春娟, 陈 垚, 等. 疫情防控期间含氯消毒剂大量使用对水生生物的影响综述[J]. 环境污染与防治, 2021, 43(5): 644-648.
[2] NESCERECKA A, JUHNA T, HAMMES F. Behavior and Stability of Adenosine Triphosphate (ATP) during Chlorine Disinfection[J]. Water Research, 2016, 101: 490-497.
[3] 毛冠男, 宋宇昊, 王莹莹. 余氯对河流水体微生物灭活效应的评价[J]. 微生物学通报, 2017,44(10):2330-2336.
[4] CHEN C-M, SHIH M L, LEE S-Z, et al. Increased Toxicity of Textile Effluents by a Chlorination Process Using Sodium Hypochlorite[J]. Water Science and Technology, 2001, 43(2): 1-8.
[5] MASILAMONI G, JESUDOSS K S, NANDAKUMAR K, et al. Lethal and Sub-lethal Effects of Chlorination on Green Mussel Perna Viridis in the Context of Biofouling Control in a Power Plant Cooling Water System[J]. Marine Environmental Research, 2002, 53(1): 65-76.
[6] WATSON K, SHAW G, LEUSCH F D L, et al. Chlorine Disinfection By-products in Wastewater Effluent: Bioassay-based Assessment of Toxicological Impact[J]. Water Research, 2012, 46(18): 6069-6083.
[7] 王文杰,安莉娜.基于WASP5氮原理的二维水量水质耦合模型及应用[J]. 长江科学院院报,2011,28(1):16-20.
[8] 周 立, 吴 琼, 姚仕明, 等. 江湖系统显式与隐式二维水动力模型比较[J]. 长江科学院院报, 2021, 38(12): 12-18.
[9] 包 嵩, 凌子坤. 基于CE-QUAL-W2模型的地表径流对滴水湖水质影响模拟[J]. 广州化工, 2012, 40(12): 158-161.
[10]汉京超. 城市雨水径流污染特征及排水系统模拟优化研究[D]. 上海: 复旦大学, 2013.
[11]王怀鋆.基于ICM模型的重庆市渝中区合流制溢流与雨水径流污染预测研究[D].重庆:重庆交通大学,2020.
[12]WU W, LU L, HUANG X, et al. An Automatic Calibration Framework Based on the InfoWorks ICM Model: The Effect of Multiple Objectives during Multiple Water Pollutant Modeling[J]. Environmental Science and Pollution Research, 2021, 28(24): 31814-31830.
[13]李帅杰, 栗玉鸿, 范 锦, 等. 城市地表水体径流污染模拟分析:以苍海湖为例[J]. 中国给水排水, 2022, 38(1): 122-128.
[14]YANG L, LI J, ZHOU K, et al. The Effects of Surface Pollution on Urban River Water Quality under Rainfall Events in Wuqing District, Tianjin, China[J]. Journal of Cleaner Production, 2021, 293: 126-136.
[15]周 川, 甄 帅, 程树辉, 等. Infoworks ICM软件在河道水环境治理水质可达性分析中的应用[J]. 市政技术, 2019, 37(3): 213-217.
基金
武汉市科技计划项目(2020020201010021)