采用原子吸收和红外光谱技术分析了EN-1离子土壤固化剂(ISS)的主要作用成分,以黄土坡滑坡滑带土扰动样为研究对象,分别对原土及经ISS处理后的土样进行了一系列物理化学试验。试验结果表明:当ISS配比(ISS与水体积比)为1∶150时,处理后土样的阳离子交换容量、可交换阳离子含量、塑性指数及比表面积降至最低。结合物理化学试验结果,分析了ISS与土体的作用机理。该作用机理为通过润湿、离子吸附、联结包裹等复杂的表面物化反应,降低土体的水敏性,提高土体的水稳定性。由于黏性土的力学性质与黏土矿物的水敏性及水稳定性关系紧密,通过ISS改善黏性土的水敏性及水稳定性为滑带土的改性和滑坡的治理提供了新思路。
Abstract
The physicochemical properties of disturbed soil sample before and after treatment by EN-1 ionic soil stabilizer (ISS) were researched by tests. AAS (atomic absorption) and FITR (infrared spectrum) technique were utilized to analyze the composition of ISS. The disturbed soil samples from the sliding zone of loess landslide was taken as research object. Test results showed that the cation exchange capacity, exchangeable cation capacity, plasticity index and specific surface area of the ISS-treated soil sample decreased to the minimum when the mixture ratio (ISS to water volume) of ISS solution is identified as 1∶150. Furthermore, the mechanism of ISS acting on the soil can be explained as follows: the soil sample’s sensitivity to water was weakened and the soil stability against water was improved through complex surface physicochemical reactions including moistening, cation exchange, absorption and coverage. Since the mechanical property of clay is related with its water sensitivity and stability, to improve the water sensitivity and stability of clay through ISS offers a new thinking for the modification of landslide soil and the landslide treatment.
关键词
EN-1土壤固化剂 /
滑带土 /
塑性指数 /
物理化学性质
Key words
EN-1 ionic soil stabilizer /
sliding zone soil /
plasticity index /
physicochemical properties
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基金
高校博士点专项科研基金(20120145110014)