为探讨外源腐殖酸对黏质农田土壤Cd活性的影响,选取2种典型腐殖酸,采用淋洗技术,通过测定农田土壤总Cd、DTPA-Cd、MgCl2-Cd的含量,研究了2种腐殖酸及其淋洗时间对土壤Cd活性的影响。研究结果表明:2种腐殖酸处理后,土壤总Cd含量基本不变,土壤DTPA-Cd含量从0.421 mg/kg降低到0.313 mg/kg,MgCl2-Cd含量从0.2 mg/kg降低到0.169 mg/kg;淋洗时间从1 d增加到5 d,土壤总Cd含量基本不变,土壤DTPA-Cd含量从0.325 mg/kg降低到0.265 mg/kg,MgCl2-Cd含量从0.196 mg/kg降低到0.165 mg/kg。因此,2种腐殖酸均对黏质农田土壤镉有一定的去除效果。
Abstract
The effects of two different extrogenous humic acids on the activity of Cd in clayey farmland were examined by measuring the content of total Cd, DTPA-Cd and MgCl2-Cd after leaching treatment. After two humic acid treatments, the total content of Cd content in the soil remained unchanged in general, the content of DTPA-Cd decreased from 0.421 mg/kg to 0.313 mg/kg, and the content of MgCl2-Cd declined from 0.2 mg/kg to 0.169 mg/kg. When leaching time increased from 1 day to 5 days, the total content of Cd also remained unchanged overall, DTPA-Cd decreased from 0.325 mg/kg to 0.265 mg/kg, and MgCl2-Cd reduced from 0.196 mg/kg to 0.165 mg/kg. In conclusion, both the exogenous humic acids could remove Cd in the soil of clayey farmland.
关键词
农田土壤 /
腐殖酸 /
淋洗技术 /
总Cd含量 /
DTPA-Cd /
MgCl2-Cd
Key words
farmland soil /
humic acid /
soil leaching /
total Cd /
DTPA-Cd /
MgCl2-Cd
{{custom_sec.title}}
{{custom_sec.title}}
{{custom_sec.content}}
参考文献
[1] 孔庆瑚, 汪再娟, 金 锋,等. 环境镉污染对人体健康影响的研究. 医学研究杂志, 2003, 32(11):20-21.
[2] LI Xiao-yu, LIU Li-juan, WANG Yu-gang, et al. Heavy Metal Contamination of Urban Soil in an Old Industrial City (Shenyang) in Northeast China. Geoderma, 2013, 192(1): 50-58.
[3] WANG Shuai-long,XU Xiang-rong,SUN Yu-xin,et al. Heavy Metal Pollution in Coastal Areas of South China: A Review.Marine Pollution Bulletin,2013,76(1/2):7-15.
[4] 黄益宗, 郝晓伟, 雷 鸣,等. 重金属污染土壤修复技术及其修复实践. 农业环境科学学报, 2013, 32(3):409-417.
[5] ADRIANO D C. Trace Elements in the Terrestrial Environment. New York: Springer-Verlag, 1986.
[6] OEHME J S. Toxicity of the Heavy Metals in Environment. New York: Dekker Incorporation, 1978.
[7] 杨 阳, 李艳玲, 王美娥,等. 湖南攸县稻米镉(Cd)富集特征及原因解析. 环境科学学报, 2017, 37(4):1502-1507.
[8] 赵晓军, 陆泗进, 许人骥,等. 土壤重金属镉标准值差异比较研究与建议. 环境科学, 2014, 35(4):1491-1497.
[9] CHAVEZ E, HE Z L, STOFFELLA P J, et al. Chemical.
Speciation of Cadmium: An Approach to Evaluate Plant-available Cadmium in Ecuadorian Soils under Cacao Production. Chemosphere, 2016, 150: 57-62.
[10]RAURET G. Extraction Procedures for the Determination of Heavy Metals in Contaminated Soil and Sediment. Talanta, 1998, 46(3):449-455.
[11]GNGREB, BEKBLET M. Zinc Release by Humic and Fulvic Acid as Influenced by pH, Complexation and DOC Sorption.. Geoderma, 2010, 159(1/2):131-138.
[12]马运宏, 范 瑜, 胡维佳,等. 重金属在土壤-作物系统中迁移分配规律的分析. 江苏环境科技, 1995(1):8-10.
[13]GBT 17141—1997,土壤质量铅、镉的测定 石墨炉原子吸收分光光度法. 北京:中国标准出版社,1997.
[14]HJ 700—2014,水质65种元素的测定 电感耦合等离子体质谱法. 北京:中国环境出版社,2014.
[15]CANARUTTO S, PETRUZZELLI G, LUBRANO L, et al. How Composting Affects Heavy Metal Content. Bio Cycle, 1991, 32: 48-50.
[16]蒋煜峰,袁建梅,卢子扬,等. 腐殖酸对污灌土壤中CU、CD、PB、ZN形态影响的研究. 西北师范大学学报(自然科学版), 2005, 41(6):42-46.
[17]王 晶,张旭东,李 彬,等.腐植酸对土壤中Cd形态的影响及利用研究.土壤通报,2002, 33(3):185-187.
[18]GB/T 23739—2009,土壤质量 有效态铅和镉的测定 原子吸收法. 北京:中国标准出版社,2009.
[19]赵永红,张 静,周 丹,等.赣南某钨矿区土壤重金属污染状况研究. 中国环境科学,2015,35(8):2477-2484.
[20]钟 正,何冠谛,何腾兵.土壤重金属污染防治研究进展.贵州农业科学,2015,43(6):202-206.
[21]YEUNG A T,GU Y Y.A Review on Techniques to Enhance Electrochemical Remediation of Contaminated Soils. Journal of Hazardous Materials, 2011, 195(52):11-29.
[22]贾 黎, 张自立. 腐殖酸对La3+,Nd3+等重金属离子混合体系吸附的研究. 中国稀土学报, 2009, 27(6):816-821.
[23]GUSIATIN Z M, KLIMIUK E. Metal (Cu, Cd and Zn) Removal and Stabilization During Multiple Soil Washing by Saponin. Chemosphere, 2012, 86(4):383-391.
[24]KARACA A, TURGAY O C, TAMER N. Effects of a Humic Deposit (Gyttja) on Soil Chemical and Microbiological Properties and Heavy Metal Availability. Biology and Fertility of Soils, 2006, 42(6): 585-592.
[25]柏宏成. 低分子有机酸、腐殖酸对土壤镉污染淋洗修复研究. 成都:四川农业大学, 2015.
基金
湖北省技术创新专项重大项目(2017ABA073);水利部公益性行业科研专项(201501019)