To make full use of the prominent green feature of slag concrete and accelerate its practical application, we adopted silica fume as the strength adjustor to investigate its effect on the mechanical strength and durability of mortars with 80% slag. We also evaluated the ecological efficiency of slag mortars. Experimental results demonstrate that silica fume is such an effective material to mitigate the retarded setting of mortars with high amount of slag due to dilutive effect. When 10% silica fume was added, the setting time of slag mortar was close to that of the control group. Moreover, silica fume has exerted prominent effects on the mechanical strength and durability of mortars. With 5% silica fume added, both the 28-day compressive strength and the flexural strength of mortar were much higher than those of mortar without silica fume. Consequently, the durability of mortar was also greatly improved by incorporating slag and silica fume into mortars, i.e., the capillary water absorption and electric flux of mortar reduced 8.83%-26.81% and 5.28%-36.87%, respectively. In summary, through the combined use of slag and silica fume as the alternative to 80% cement to prepare mortars, we significantly ameliorated the performance of slag mortars as well as its ecological efficiency, hence providing theoretical basis for the application and development of concrete with high volume of slag.
Key words
slag mortar /
silica fume /
mechanical strength /
durability /
ecological efficiency
{{custom_sec.title}}
{{custom_sec.title}}
{{custom_sec.content}}
References
[1] RAFAT S, MOHAMMAD I K. Supplementary Cementing Materials[M].Heidelberg: Springer, 2011.
[2] 林宗寿. 矿渣基生态水泥[M]. 北京: 中国建材工业出版社, 2018.
[3] JOHARI M A M, BROOKS J J, KABIR S, et al. Influence of Supplementary Cementitious Materials on Engineering Properties of High Strength Concrete[J]. Construction and Building Materials, 2010, 25(5): 2639-2648.
[4] RASHAD A M, SADEK D M,et al. An Investigation on Portland Cement Replaced by High-volume GGBS Pastes Modified with Micro-sized Metakaolin Subjected to Elevated Temperatures[J]. International Journal of Sustainable Built Environment, 2017, 6(1): 91-101.
[5] SAJEDI F.Mechanical Activation of Cement-Slag Mortars[J]. Construction and Building Materials,2011,26(1):41-48.
[6] SIDDIQUE R,BENNACER R.Use of Iron and Steel Industry By-product (GGBS) in Cement Paste and Mortar[J]. Resources Conservation and Recycling,2012,69(12):29-34.
[7] FU X, HOU W, YANG C, et al. Studies on Portland Cement with Large Amount of Slag[J]. Cement and Concrete Research, 2000, 30(4): 645-649.
[8] ZHANG M, ISLAM J. Use of Nano-Silica to Reduce Setting Time and Increase Early Strength of Concretes with High Volumes of Fly Ash or Slag[J]. Construction and Building Materials, 2012, 34(5): 650-662.
[9] HOSAN A, SHAIKH F U A. Influence of Nano-CaCo3 Addition on the Compressive Strength and Microstructure of High Volume Slag and High Volume Slag-Fly Ash Blended Pastes[J]. Journal of Building Engineering, 2020, 27: 100929.
[10] El-CHABIB H, IBRAHIM A. The Performance of High-Strength Flowable Concrete Made with Binary, Ternary, or Quaternary Binder in Hot Climate[J]. Construction and Building Materials, 2013, 47(10): 245-253.
[11] SAJEDI F, RAZAK H A. Effects of Thermal and Mechanical Activation Methods on Compressive Strength of Ordinary Portland Cement-Slag Mortar[J]. Materials and Design, 2010, 32(2): 984-995.
[12] ASTM C191, Standard Test Method for Time of Setting of Hydraulic Cement by Vicat Needle[S]. Pennsylvania: ASTM International, 1999.
[13] ASTM C348, Standard Test Method for Flexural Strength of Hydraulic-Cement Mortars[S]. Pennsylvania: ASTM International, 2002.
[14] ASTM C1202, Standard Test Method for Electrical Indication of Concrete's Ability to Resist Chloride Ion Penetration[S]. Pennsylvania: ASTM International, 2012.
[15] ASTM C1585, Standard Test Method for Measurement of Rate of Absorption of Water by Hydraulic-Cement Concretes[S]. Pennsylvania: ASTM International, 2011.
[16] HAMIDI M, KACIMI L,CYR M, et al. Evaluation and Improvement of Pozzolanic Activity of Andesite for Its Use in Eco-efficient Cement[J]. Construction and Building Materials, 2013, 47(7): 1268-1277.
[17] ABDELKADER B,EI-HADJ K,KARIM E. Efficiency ofGranulated Blast Furnace Slag Replacement of Cement According to the Equivalent Binder Concept[J]. Cement and Concrete Composites, 2009, 32(3): 226-231.
[18] 蒋家奋. 矿渣微粉在水泥混凝土中应用的概述[J]. 混凝土与水泥制品, 2002, 29(3): 3-6.
[19] LI K, ZENG Q, LUO M, et al. Effect of Self-desiccation on the Pore Structure of Paste and Mortar Incorporating 70% GGBS[J]. Construction and Building Materials, 2014, 51(1): 329-337.
[20] RASHAD A M.An Investigation on Very High Volume Slag Pastes Subjected to Elevated Temperatures[J]. Construction and Building Materials,2015,74(1): 249-258.
[21] RICHARDSON I G.Tobermorite/Jennite-and Tobermorite/Calcium Hydroxide-based Models for the Structure of C-S-H: Applicability to Hardened Pastes of Tricalcium Silicate, Β-Dicalcium Silicate, Portland Cement, and Blends of Portland Cement with Blast-Furnace Slag, Metakaolin, or Silica Fume[J]. Cement and Concrete Research, 2004, 34(9): 1733-1777.
[22] DB 31/581—2012,矿渣粉单位产品能源消耗限额[J]. 北京:中国质检出版社, 2013, 32(1): 6-10.
[23] 段西京. 浅谈高纯度硅粉的深加工[J]. 铁合金,2015,46(9): 27-29.