生物基固化轻质红砂岩渣土的机理及强度特性

温树杰, 徐昌宜, 黄翔, 黄英豪, 傅鹤林

长江科学院院报 ›› 2025, Vol. 42 ›› Issue (8) : 128-134.

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PDF(6146 KB)
长江科学院院报 ›› 2025, Vol. 42 ›› Issue (8) : 128-134. DOI: 10.11988/ckyyb.20240595
岩土工程

生物基固化轻质红砂岩渣土的机理及强度特性

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Mechanisms and Strength Characteristics of Bio-based Solidified Lightweight Red Sandstone Residual Soil

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摘要

为实现红砂岩渣土在工程中低碳循环利用的目标,提出了采用微生物诱导碳酸钙沉淀(MICP)技术制备轻质红砂岩固化土的方法,开展了对轻质红砂岩固化土固化机理的研究,分析了发泡聚苯乙烯(EPS)质量掺量和胶结液浓度对轻质红砂岩固化土强度的影响,并在此基础上探究了轻质红砂岩固化土压缩破坏特征,从强度分析与破坏特征两方面验证了轻质红砂岩固化土的胶结机理。研究结果表明:轻质红砂岩固化土中的CaCO3晶体在EPS颗粒上沉积较少,在土颗粒间形成的大范围胶结起到支撑轻质红砂岩固化土强度的主要作用;当EPS颗粒质量掺量为0.375%、胶结液浓度为1.5 mol/L时,轻质红砂岩固化土重度为14.3 kN/m3,抗压强度达到0.76 MPa,满足泡沫轻质土工程规范;EPS质量掺量的增加使轻质红砂岩固化土破坏特征从剪切破坏转化为鼓胀破坏。

Abstract

[Objective] A method for preparing solidified lightweight red sandstone soil using microbial-induced calcium carbonate precipitation (MICP) technology was proposed for the recycle use of red sandstone residual soil in engineering. A design study was conducted on bio-based solidified lightweight red sandstone soil to investigate the solidification mechanism of the modified material. The effects of expanded polystyrene (EPS) mass content and cementation solution concentration on the strength of the lightweight solidified soil are analyzed. Based on this, the compression failure characteristics of the solidified lightweight red sandstone soil are studied, and its cementation mechanism is validated through both strength analysis and failure characteristics. [Methods] Bacillus pasteurii was selected as the target strain, and cementation solutions with concentrations ranging from 0.5 to 2.0 mol/L were prepared. Solidified lightweight red sandstone soil samples with EPS contents ranging from 0% to 1.125% were prepared. The internal microstructure of the modified red sandstone residual soil was analyzed using X-ray diffraction (XRD) and scanning electron microscopy (SEM). Additionally, its mechanical properties were evaluated through slow shear tests and uniaxial compression tests. [Results] After MICP treatment, a substantial amount of calcite-type CaCO3 precipitates was generated within the red sandstone residual soil. These CaCO3 crystals formed a continuous and dense cementation network between soil particles, serving as the primary contributor to the strength of the solidified lightweight red sandstone soil. In contrast, only sparse crystal clusters were observed on the surfaces of hydrophobic EPS particles. When the cementation solution concentration was 1.5 mol/L and the EPS content was 0.375%, the solidified lightweight red sandstone soil samples exhibited the optimal performance combination. The compressive strength reached 0.76 MPa, meeting the standard requirement (≥0.6 MPa) for foam lightweight soil. The bulk density was 14.3 kN/m3, representing a 13% reduction compared to the undisturbed soil. Additionally, the internal friction angle and cohesion increased by 39% and 17%, respectively. Failure mode analysis revealed that samples with low EPS content (≤0.375%) exhibited typical brittle shear failure, with cracks propagating in a “Y” shape. In contrast, samples with high EPS content (≥1.125%) showed bulging failure, accompanied by surface spalling and debris detachment. [Conclusions] The combination of microbial solidification technology and EPS lightweight foam soil technology has effectively solidified lightweight red sandstone soil, overcoming the high energy consumption limitations of traditional cement-based solidification methods. A quantitative relationship between “cementation solution concentration, EPS content, and mechanical properties” was established. The proposed optimal mix ratio (1.5 mol/L cementation solution + 0.375% EPS) combines both lightweight characteristics (bulk density of 14.3 kN/m3) and high strength (0.76 MPa). This study provides a low-carbon and environmentally friendly solution for the resource utilization of red sandstone residual soil, demonstrating significant application value in engineering fields such as subgrade filling.

关键词

微生物诱导碳酸沉淀(MICP) / 发泡聚苯乙烯(EPS) / 强度 / 破坏特征 / 微观结构

Key words

MICP / expanded polystyrene / strength / failure characteristics / microstructure

引用本文

导出引用
温树杰, 徐昌宜, 黄翔, . 生物基固化轻质红砂岩渣土的机理及强度特性[J]. 长江科学院院报. 2025, 42(8): 128-134 https://doi.org/10.11988/ckyyb.20240595
WEN Shu-jie, XU Chang-yi, HUANG Xiang, et al. Mechanisms and Strength Characteristics of Bio-based Solidified Lightweight Red Sandstone Residual Soil[J]. Journal of Changjiang River Scientific Research Institute. 2025, 42(8): 128-134 https://doi.org/10.11988/ckyyb.20240595
中图分类号: TU446 (红粘土与地基)   

参考文献

[1]
赵明华, 邓觐宇, 曹文贵. 红砂岩崩解特性及其路堤填筑技术研究[J]. 中国公路学报, 2003, 16(3): 1-5.
摘要
结合某高速公路大型模拟试验路堤及实体工程试验路段试验研究,从研究红砂岩的化学成分与结构特征入手,深入探讨了红砂岩崩解试验方法及其崩解机理与特性,从而提出了红砂岩的有效工程分类方法,并在此基础上,深入研究了红砂岩作为路用材料的路堤填筑技术,进而确定出红砂岩路基填
(ZHAO Ming-hua, DENG Jin-yu, CAO Wen-gui. Study of the Disintegration Character of Red Sandstone and the Construction Techniques of Red Sandstone Embankment[J]. China Journal of Highway and Transport, 2003, 16(3): 1-5.(in Chinese))
结合某高速公路大型模拟试验路堤及实体工程试验路段试验研究,从研究红砂岩的化学成分与结构特征入手,深入探讨了红砂岩崩解试验方法及其崩解机理与特性,从而提出了红砂岩的有效工程分类方法,并在此基础上,深入研究了红砂岩作为路用材料的路堤填筑技术,进而确定出红砂岩路基填
[2]
刘芙容, 石林. 红砂岩崩解特性及其路堤填筑施工技术研究[J]. 科技创新导报, 2022, 19 (28): 24-27.
(LIU Fu Rong, SHI Lin. Study on Disintegrating Characteristics of Red Sandstone and Construction Technology of Embankment Filling[J]. Science and Technology Innovation Herald, 2022, 19 (28): 24-27 (in Chinese))
[3]
王协群, 匡文壮, 韩仲, 等. 膨胀土中EPS缓冲层-悬臂式挡墙支护结构的受力变形数值模拟[J]. 长江科学院院报, 2022, 39(7): 78-86.
摘要
针对膨胀土中墙后铺设聚苯乙烯泡沫(EPS)缓冲层的悬臂式挡墙,探究了膨胀土因降雨入渗产生膨胀时EPS缓冲层的减压效果。对南阳中膨胀土开展膨胀特性试验,确定其在侧限和竖向荷载作用下的膨胀系数;在此基础上,利用ABAQUS数值软件对膨胀土-EPS缓冲层-悬臂式挡墙体系开展数值分析,研究了EPS缓冲层的厚度与弹性模量及与墙体和膨胀土间摩擦对该支护结构受力变形特征的影响规律。结果表明:EPS缓冲层能有效减小悬臂式挡墙上的侧压力并改变墙背土压力的分布;厚度较厚、弹性模量较低的EPS缓冲层减载效果更好;EPS缓冲层与墙体、膨胀土之间的摩擦影响墙背侧压力的分布,但不影响侧压力的合力大小;EPS缓冲层的压缩刚度与其减载性能成反比。
(WANG Xie-qun, KUANG Wen-zhuang, HAN Zhong, et al. Numerical Simulation of the Force and Deformation Characteristics of Cantilever Retaining Structure with EPS Buffer in Expansive Soil[J]. Journal of Yangtze River Scientific Research Institute, 2022, 39(7): 78-86.(in Chinese))
The decompression effect of expanded polystyrene (EPS) buffer layer in cantilever retaining wall was examined when the expansive soil expands due to rainfall infiltration. The expansion characteristics of Nanyang expansive soil were tested to determine its expansion coefficient under lateral and vertical loads. On this basis, the expansive soil-EPS buffer layer-cantilever retaining wall system was numerically simulated using ABAQUS to explore the influences of EPS buffer layer (thickness, elastic modulus, and interface friction) on the stress and deformation of the system. Numerical results indicate that EPS buffer layer effectively reduces the lateral pressure on the cantilever retaining wall and changes the distribution of soil pressure on the wall back. The EPS buffer layer with larger thickness and lower elastic modulus has better effect. The friction between EPS buffer layer, wall and expansive soil affects the distribution of lateral pressure on the wall, but does not affect the resultant force of the lateral pressure. In addition, the compression stiffness of EPS buffer layer is inversely proportional to its load reduction performance.
[4]
MOHAJERANI A, ASHDOWN M, ABDIHASHI L, et al. Expanded Polystyrene Geofoam in Pavement Construction[J]. Construction and Building Materials, 2017, 157: 438-448.
[5]
PUPPALA A J, RUTTANAPORAMAKUL P, CONGRESS S S C. Design and Construction of Lightweight EPS Geofoam Embedded Geomaterial Embankment System for Control of Settlements[J]. Geotextiles and Geomembranes, 2019, 47(3): 295-305.
[6]
RAMLI SULONG N H, MUSTAPA S A S, ABDUL RASHID M K. Application of Expanded Polystyrene (EPS) in Buildings and Constructions: A Review[J]. Journal of Applied Polymer Science, 2019, 136(20): 47529.
[7]
刘浩林, 李丹, 胡波, 等. 基于MICP技术改良的膨胀土膨胀特性试验研究[J]. 长江科学院院报, 2022, 39(6): 150-156.
摘要
为了探究微生物诱导碳酸钙沉淀(MICP)技术改良膨胀土膨胀特性的效果和作用机理,利用产脲酶菌CGMCC 1.368 7,开展了MICP拌和法处理膨胀土的膨胀特性试验。通过正交试验研究了反应液配比和Ca<sup>2+</sup>浓度对MICP拌和法处理膨胀土自由膨胀率、无荷膨胀率、CaCO<sub>3</sub>百分生成量的影响及其变化规律,揭示了MICP改良膨胀土的微观机理。结果表明:经MICP拌和法处理后,膨胀土的膨胀特性得到显著改善;当反应液配比为1∶1、Ca<sup>2+</sup>浓度为2.0 mol/L时,膨胀土自由膨胀率最大降低了44.4%;当反应液配比为1∶3、Ca<sup>2+</sup>浓度为2.0 mol/L时,体膨胀率减小了92.2%,膨胀含水率降低了24.9%。MICP技术通过胶结土颗粒、充填土体孔隙和离子置换作用,降低膨胀土颗粒的亲水性,减小土颗粒间的排斥作用,减弱膨胀土的膨胀势。研究成果验证了基于MICP技术拌和法改良膨胀土膨胀特性的可行性。
(LIU Hao-lin, LI Dan, HU Bo, et al. Experimental Study on Improving the Swelling Characteristics of Expansive Soil Using MICP Technology[J]. Journal of Yangtze River Scientific Research Institute, 2022, 39(6): 150-156.(in Chinese))
The effectiveness and mechanism of MICP (Microbial Induced Calcium carbonate Precipitation) improving the expansion characteristics of expansive soil were investigated via test of expansive soil mixed with urease-producing bacteria CGMCC 1.368 7. The effects of reaction solution ratio and Ca<sup>2+</sup> molar concentration on the free expansion rate, unloaded expansion rate, and percentage generation of CaCO<sub>3</sub> of expansive soil treated with MICP were studied by orthogonal experiments, and the microscopic properties of MICP-modified expansive soil were revealed. The swelling characteristics of expansive soil treated with MICP can be improved remarkably: when the ratio of reaction solution is 1∶1 and the concentration of Ca<sup>2+</sup> is 2.0 mol/L, the free expansion rate of expansive soil is reduced by 44.4% at most; when the ratio of the reaction solution is 1∶3 and the concentration of Ca<sup>2+</sup> is 2.0 mol/L, the volumetric expansion rate is reduced by 92.2%, and the expansion moisture content is reduced by 24.9%. MICP technology reduces the hydrophilicity of expansive soil particles, hinders the repulsion between soil particles, and weakens the expansion potential of expansive soil by cementing soil particles, filling soil pores and ion replacement. The research results verify the feasibility of improving the swelling properties of expansive soil by mixing based on MICP technology.
[8]
刘汉龙, 肖鹏, 肖杨, 等. 微生物岩土技术及其应用研究新进展[J]. 土木与环境工程学报(中英文), 2019, 41(1): 1-14.
(LIU Han-long, XIAO Peng, XIAO Yang, et al. State-of-the-art Review of Biogeotechnology and Its Engineering Applications[J]. Journal of Civil and Environmental Engineering, 2019, 41(1): 1-14.(in Chinese))
[9]
张茜, 叶为民, 刘樟荣, 等. 基于生物诱导碳酸钙沉淀的土体固化研究进展[J]. 岩土力学, 2022, 43(2):345-357.
(ZHANG Qian, YE Wei-min, LIU Zhang-rong, et al. Advances in Soil Cementation by Biologically Induced Calcium Carbonate Precipitation[J]. Rock and Soil Mechanics, 2022, 43(2): 345-357.(in Chinese))
[10]
TANG C, PAN X, CHENG Y, et al. Improving Hydro-mechanical Behavior of Loess by a Bio-strategy[J]. Biogeotechnics, 2023, 1(2): 100024.
[11]
WANG S, SHEN T, TIAN R, et al. Uniformity Evaluation and Improvement Technology of Sandy Clayey Purple Soil Enhanced through Microbially-induced Calcite Precipitation[J]. Biogeotechnics, 2023, 1(4): 100048.
[12]
WANG X, LI C, SHI Y, et al. Improvements in Saline Soil and the Law of Water-salt Transport Based on Salt Inhibition Using MICP Technology[J]. Biogeotechnics, 2024, 2(1): 100055.
[13]
李驰, 王硕, 王燕星, 等. 沙漠微生物矿化覆膜及其稳定性的现场试验研究[J]. 岩土力学, 2019, 40(4): 1291-1298.
(LI Chi, WANG Shuo, WANG Yan-xing, et al. Field Experimental Study on Stability of Bio-mineralization Crust in the Desert[J]. Rock and Soil Mechanics, 2019, 40(4): 1291-1298.(in Chinese))
[14]
刘璐, 沈扬, 刘汉龙, 等. 微生物胶结在防治堤坝破坏中的应用研究[J]. 岩土力学, 2016, 37(12):3410-3416.
(LIU Lu, SHEN Yang, LIU Han-long, et al. Application of Bio-cement in Erosion Control of Levees[J]. Rock and Soil Mechanics, 2016, 37(12):3410-3416.(in Chinese))
[15]
XIANG J, SONG Y, SHU H, et al. Expanded Polystyrene (EPS) Particles as a Carrier to Improve the Growth of Microorganisms in Concrete[J]. Journal of Cleaner Production, 2022, 369: 133363.
[16]
XIAO Y, HE X, LIU H. New Lightweight Geomaterials: Biocemented Sand Mixed with Expanded Polystyrene Beads[J]. Science China Technological Sciences, 2017, 60(7): 1118-1120.
[17]
JTG 3430—2020, 公路土工试验规程[S]. 北京: 人民交通出版社, 2020.
(JTG 3430—2020, Test Methods of Soils for Highway Engineering[S]. Beijing: China Communications Press, 2020.(in Chinese))
[18]
陈忠平, 孙仲均, 钱争晖. 泡沫轻质土充填技术及应用[J]. 施工技术, 2011, 40(10):74-76.
(CHEN Zhong-ping, SUN Zhong-jun, QIAN Zheng-hui. Filling Technology and Application of Foamed Light-weight Soil[J]. Construction Technology, 2011, 40(10): 74-76.(in Chinese))
[19]
刘志明, 孙益成, 冯清鹏. MICP胶结液中尿素过量的影响研究[J]. 防灾减灾工程学报, 2020, 40(4):574-580.
(LIU Zhi-ming, SUN Yi-cheng, FENG Qin- peng, et al. Study on Influence of Excess Urea in MICP Cementation Solution[J]. Journal of Disaster Prevention and Mitigation Engineering, 2020, 40(4):574-580.(in Chinese))
[20]
CECS 249—2008, 现浇泡沫轻质土技术规程[S]. 北京: 中国计划出版社, 2009.
(CECS 249—2008, Technical Specification for Cast-in-situ Foamed Lightweight Soil[S]. Beijing: China Planning Press, 2009.(in Chinese))

基金

江西省研究生创新专项资金项目(YC2022-S667)

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