高延性固化粉土的力学特性及微观结构

张超杰, 洪瑜泽, 程泽海, 金鎏君, 凌豪俊

长江科学院院报 ›› 2025, Vol. 42 ›› Issue (5) : 155-164.

PDF(8399 KB)
PDF(8399 KB)
长江科学院院报 ›› 2025, Vol. 42 ›› Issue (5) : 155-164. DOI: 10.11988/ckyyb.20240418
岩土工程

高延性固化粉土的力学特性及微观结构

作者信息 +

Mechanical Properties and Microstructure of High Ductility Solidified Silt

Author information +
文章历史 +

摘要

针对钱塘江海塘地基粉土黏聚力较小、抗渗能力弱、易被水侵蚀流失等特点,开展不同固化剂掺量、不同含水率和龄期的固化粉土无侧限抗压强度试验、渗透试验、扫描电镜试验(SEM)和X射线衍射仪试验(XRD),运用Image J软件机器学习处理电镜图像,研究改性固化粉土的力学特性和微观特征,探讨其固化机理、强度、渗透系数的变化规律及微观特征与宏观力学性能之间的相关性,使其达到高延性目的。结果表明:改性固化粉土的延塑性和抗渗性明显提升,得到最佳固化剂配比;与普通固化粉土相比,改性固化粉土中检测出有机高分子化合物,扫描电镜试验(SEM)显示水化物和片状高聚物薄片包裹颗粒;改性固化粉土的孔隙数与强度的相关性并不显著,破坏应变与孔隙率成正相关关系,渗透养护后的固化粉土孔隙数和孔隙率比渗透养护前降低。

Abstract

[Objectives] The silt foundations of Qiantang River seawalls exhibit weak impermeability and are prone to water erosion and loss. During periods of strong tidal bores and floods, soil flowing and piping are likely to occur, leading to seawall defects and seepage deformation or cavities in the seawall foundation. To address these issues, solidification and improvement measures are necessary. [Methods] This paper focuses on the different improvement properties of curing agents and employs a controlled-variable method to conduct silt solidification ratio experiments. The improvement of solidified silt were analyzed through unconfined compressive strength tests and permeability tests. XRD was employed for changes in mineral composition and chemical products before and after silt solidification, and SEM tests were conducted to observe the microstructural changes caused by the addition of chemical reagents. ImageJ software with machine learning capabilities was utilized to process SEM images to quantify the correlation between mechanical properties and microstructural characteristics. [Results] The optimal solidifying agent composition consisted of 4% cement, 1% fly ash, 1% lignin, 1% HV, and 1% CMC. This formulation resulted in a 28-fold increase in failure strain and a lower permeability coefficient than that of the original silt. In a permeable environment, the permeability coefficient of the solidified silt gradually decreased over time until it stabilized. SEM revealed hydrated calcium silicate (C-S-H) and ettringite (AFt) from cement hydration in the solidified silt, as well as glassy silica-alumina in a spherical fly ash morphology filling the pores. Quantitative analysis using Image J software indicated that the C4H1-solidified silt exhibited the greatest increase in failure strain and porosity, achieving the best ductility effect. Curve-fitting uncover that the correlation between pore count and strength in the modified solidified silt was not significant, while failure strain showed a positive correlation with porosity. [Conclusion] By transcending the limitations of traditional research, which often focuses on a single property (strength or impermeability), this study achieves synergistic improvement of both high ductility and impermeability, providing a more comprehensive solution for engineering applications. Additionally, the use of ImageJ software for quantitative analysis of pore structure has revealed a positive correlation between porosity and failure strain, offering a microscopic explanation for macroscopic properties.

关键词

高延性固化粉土 / 微观结构 / 破坏应变 / 强度 / 渗透性

Key words

high ductility solidified silt / microstructure / failure strain / strength / permeability

引用本文

导出引用
张超杰, 洪瑜泽, 程泽海, . 高延性固化粉土的力学特性及微观结构[J]. 长江科学院院报. 2025, 42(5): 155-164 https://doi.org/10.11988/ckyyb.20240418
ZHANG Chao-jie, HONG Yu-ze, CHENG Ze-hai, et al. Mechanical Properties and Microstructure of High Ductility Solidified Silt[J]. Journal of Changjiang River Scientific Research Institute. 2025, 42(5): 155-164 https://doi.org/10.11988/ckyyb.20240418
中图分类号: TU473   

参考文献

[1]
庞文台, 申向东. 复合水泥土抗渗性能的实验研究[J]. 硅酸盐通报, 2012, 31(6): 1617-1620, 1625.
摘要
水泥土已经广泛应用于公路、建筑、水利等领域,本文针对内蒙古河套地区粉质粘土,着重探讨水泥掺量、养护龄期、及掺加粉煤灰、石灰对水泥土抗渗性的影响,并通过电镜试验,分析水泥土及复合水泥土微观结构的变化.结果表明水泥掺量越大、龄期越长,水泥土抗渗性能越好,其微观原因是水泥土孔隙随着龄期的增长,数量减少,尺寸减小.单掺粉煤灰对水泥土抗渗性能影响较小,但是加入石灰就可以激发粉煤灰的火山灰作用,生成不溶于水的水化硅酸钙.本文针对河套地区粉质粘土得到抗渗性能良好的配比:水∶水泥∶粉煤灰∶石灰∶粉质粘土=1.45∶1.00∶0.15∶0.0375∶7.3625.这种配比相对粉煤灰水泥土提高抗渗性能50%以上.
(PANG Wen-tai, SHEN Xiang-dong. Study on Impervious Performance of Cement-soil[J]. Bulletin of the Chinese Ceramic Society, 2012, 31(6): 1617-1620, 1625.) (in Chinese)
水泥土已经广泛应用于公路、建筑、水利等领域,本文针对内蒙古河套地区粉质粘土,着重探讨水泥掺量、养护龄期、及掺加粉煤灰、石灰对水泥土抗渗性的影响,并通过电镜试验,分析水泥土及复合水泥土微观结构的变化.结果表明水泥掺量越大、龄期越长,水泥土抗渗性能越好,其微观原因是水泥土孔隙随着龄期的增长,数量减少,尺寸减小.单掺粉煤灰对水泥土抗渗性能影响较小,但是加入石灰就可以激发粉煤灰的火山灰作用,生成不溶于水的水化硅酸钙.本文针对河套地区粉质粘土得到抗渗性能良好的配比:水∶水泥∶粉煤灰∶石灰∶粉质粘土=1.45∶1.00∶0.15∶0.0375∶7.3625.这种配比相对粉煤灰水泥土提高抗渗性能50%以上.
[2]
陈萌, 杨国录, 余亮英. 粉煤灰和NaOH固化稳定化受污淤泥试验研究[J]. 华中科技大学学报(自然科学版), 2013, 41(10): 123-127.
(CHEN Meng, YANG Guo-lu, YU Liang-ying. Experimental Study on Solidification and Stabilization of Polluted Silt Using Fly Ash and Sodium Hydroxide[J]. Journal of Huazhong University of Science and Technology (Natural Science Edition), 2013, 41(10): 123-127.) (in Chinese)
[3]
OUHADI V R, YONG R N, AMIRI M, et al. Pozzolanic Consolidation of Stabilized Soft Clays[J]. Applied Clay Science, 2014, 95: 111-118.
[4]
GHANIZADEH A R, RAHROVAN M. Modeling of Unconfined Compressive Strength of Soil-RAP Blend Stabilized with Portland Cement Using Multivariate Adaptive Regression Spline[J]. Frontiers of Structural and Civil Engineering, 2019, 13(4): 787-799.

The recycled layer in full-depth reclamation (FDR) method is a mixture of coarse aggregates and reclaimed asphalt pavement (RAP) which is stabilized by a stabilizer agent. For design and quality control of the final product in FDR method, the unconfined compressive strength of stabilized material should be known. This paper aims to develop a mathematical model for predicting the unconfined compressive strength (UCS) of soil-RAP blend stabilized with Portland cement based on multivariate adaptive regression spline (MARS). To this end, two different aggregate materials were mixed with different percentages of RAP and then stabilized by different percentages of Portland cement. For training and testing of MARS model, total of 64 experimental UCS data were employed. Predictors or independent variables in the developed model are percentage of RAP, percentage of cement, optimum moisture content, percent passing of #200 sieve, and curing time. The results demonstrate that MARS has a great ability for prediction of the UCS in case of soil-RAP blend stabilized with Portland cement (R2 is more than 0.97). Sensitivity analysis of the proposed model showed that the cement, optimum moisture content, and percent passing of #200 sieve are the most influential parameters on the UCS of FDR layer.

[5]
王东星, 王宏伟, 肖杰, 等. 活性MgO-粉煤灰软土固化材料强度与机理研究[J]. 中国矿业大学学报, 2018, 47(4): 879-884.
(WANG Dong-xing, WANG Hong-wei, XIAO Jie, et al. Strength and Micromechanism of Reactive MgO-activated Fly Ash as an Alternative Soft Soil Stabilizer[J]. Journal of China University of Mining & Technology, 2018, 47(4): 879-884.) (in Chinese)
[6]
王东星, 何福金. CO2碳化-矿渣/粉煤灰协同固化土效果与机制研究[J]. 岩石力学与工程学报, 2020, 39(7): 1493-1502.
(WANG Dong-xing, HE Fu-jin. Investigation on Performance and Mechanism of CO2 Carbonated Slag/Fly Ash Solidified Soils[J]. Chinese Journal of Rock Mechanics and Engineering, 2020, 39(7): 1493-1502.) (in Chinese)
[7]
朱剑锋, 汪正清, 陶燕丽, 等. 电石渣-草木灰复合固化剂固化废弃软土微观特性研究[J]. 土木工程学报, 2023(10):180-189.
(ZHU Jian-feng, WANG Zheng-qing, TAO Yan-li, et al. Study on Micro-characteristics of Waste Soft Soil Solidified by Carbide Slag-plant Ash Composite Curing Agent[J]. China Industrial Economics, 2023(10):180-189.) (in Chinese)
[8]
FALCIGLIA P P, AL-TABBAA A, VAGLIASINDI F G A. Development of a Performance Threshold Approach for Identifying the Management Options for Stabilisation/Solidification of Lead Polluted Soils[J]. Journal of Environmental Engineering and Landscape Management, 2014, 22(2): 85-95.
[9]
MUTHUKKUMARAN K, ANUSUDHA V. Study on Behavior of Copper Slag and Lime-Treated Clay under Static and Dynamic Loading[J]. Journal of Materials in Civil Engineering, 2020, Doi: 10.1061/(ASCE)MT.1943-5533.0003259.
[10]
马启郁. 高含水率粉土路基固化改良机理及应用研究[D]. 阜新: 辽宁工程技术大学, 2020.
(MA Qi-yu. Research on Improving Mechanism and Application of High Water Content Silt Solidification[D]. Fuxin:Liaoning University of Engineering and Technology, 2020.) (in Chinese)
[11]
屠晨阳. 不同外掺剂时砂质粉土的固化试验研究[J]. 低温建筑技术, 2018, 40(5): 98-102.
(TU Chen-yang. Experimental Study on the Solidification of Sandy Silt with Different Additives[J]. Low Temperature Architecture Technology, 2018, 40(5): 98-102.) (in Chinese)
[12]
王超杰, 李逢源, 郭成超, 等. 高聚物固化粉土的力学特性与固结机理[J]. 建筑材料学报, 2022, 25(6):598-606.
(WANG Chao-jie, LI Feng-yuan, GUO Cheng-chao, et al. Mechanical Properties and Consolidation Mechanism of Polymer Solidified Silt Soil[J]. Journal of Building Materials, 2022, 25(6): 598-606.) (in Chinese)
[13]
董金梅, 朱华, 黄春霞, 等. 改性粉土的破坏模式及应力-应变特性[J]. 南京工业大学学报(自然科学版), 2015, 37(3): 74-78.
(DONG Jin-mei, ZHU Hua, HUANG Chun-xia, et al. Failure Mode and Stress-strain Characteristics of Modified Silt[J]. Journal of Nanjing Tech University (Natural Science Edition), 2015, 37(3): 74-78.) (in Chinese)
[14]
董金梅, 王沛, 柴寿喜, 等. 高分子材料SH固化轻质土的压缩变形特性[J]. 应用基础与工程科学学报, 2013, 21(2):267-275.
(DONG Jin-mei, WANG Pei, CHAI Shou-xi, et al. Compression Deformation Characteristics of Polymer SH Solidified Lightweight Soill[J]. Journal of Basic Science and Engineering, 2013, 21(2): 267-275.) (in Chinese)
[15]
刘尧伍. 无磺木质素加固碳酸型盐渍土工程效果与机理研究[D]. 长春: 吉林大学, 2020.
(LIU Yao-wu. Effective Assessment and Stabilization Mechanism of Sulfur-Free Lignin-Stabilized Soda Alkaline Soil[D]. Changchun: Jilin University, 2020 ) (in Chinese)
[16]
TINGLE J S, SANTONI R L. Stabilization of Clay Soils with Nontraditional Additives[J]. Transportation Research Record: Journal of the Transportation Research Board, 2003, 1819(1): 72-84.
[17]
TA’NEGONBADI B, NOORZAD R. Stabilization of Clayey Soil Using Lignosulfonate[J]. Transportation Geotechnics, 2017, 12: 45-55.
[18]
赵之, 杨秀娟, 石庆红, 等. 磷石膏/木质素固化铅污染土的无侧限抗压强度[J]. 土木与环境工程学报(中英文), 2025, 47(1):89-99.
(ZHAO Zhi, YANG Xiu-juan, SHI Qing-hong, et al. Unconfined Compressive Strength of Phosphogypsum/Ligninsolidified Lead Contaminated Soil[J]. Journal of Civil and Environmental Engineering (Chinese and English), 2025, 47(1):89-99.) (in Chinese)
[19]
刘松玉, 张涛, 蔡国军. 工业废弃木质素固化改良粉土路基技术与应用研究[J]. 中国公路学报, 2018, 31(3): 1-11.
摘要
为研究工业废弃木质素改良粉土路基技术的可行性,通过室内无侧限抗压强度、水稳性和干湿循环试验,分析掺量(质量分数)、龄期等因素对木质素改良粉土力学特性和耐久性的影响,并与石灰改良进行对比;基于微观分析结果,阐明木质素改良土体的机理;同时开展木质素改良粉土路基填料现场试验,对改良路基土进行加州承载比、回弹弯沉值、轻型动力触探等路用性能测试和环境影响评价。研究结果表明:木质素可有效提高粉土的抗压强度和耐久性,其改良粉土的最优掺量为12%,28 d龄期养护12%掺量试样的水稳系数为0.52,经历4次干湿循环后,质量损失率低于20%,木质素改良粉土的耐久性能显著优于石灰土;木质素与粉土主要发生了水解反应、质子化反应和静电引力作用,最终形成致密稳定的土体结构;15 d龄期养护后,12%掺量木质素改良路基粉土的路用性能指标均优于8%掺量生石灰土,回弹弯沉值在1 mm以内,贯入阻力随养护龄期和贯入深度的变化可表征改良路基土的强度特征;木质素改良路基粉土的土壤质量符合二级标准,论证了木质素固化改良粉土路基技术的可行性和环境友好性。
(LIU Song-yu, ZHANG Tao, CAI Guo-jun. Research on Technology and Engineering Application of Silt Subgrade Solidified by Lignin-based Industrial By-product[J]. China Journal of Highway and Transport, 2018, 31(3): 1-11.) (in Chinese)
To investigate the feasibility of the silt subgrade solidified by lignin-based industrial by-product, a series of laboratory tests including unconfined compression strength test, water resistance test, and wetting-drying test were conducted to analyze the effect of the additive content and the curing period on mechanical properties and durability of lignin treated silt. The improvement of lignin was also compared with the lime. Based on the results of microscopic analysis, the stabilization mechanism of lignin solidified silt was explained. Moreover, the field test of subgrade silt solidified by lignin was carried out, whilst the road performance tests including California bearing capacity ratio (CBR) test, rebound deflection value test, dynamic cone penetrometer (DCP) test and evaluation of environmental impact of solidified silt were conducted. The results show that lignin can effectively improve the compression strength and durability of silt. The optimum percentage of lignin of the silt is 12%. The specimen treated with 12% lignin after 28 days of curing has a water resistance coefficient of 0.52. And after suffering 4 times wetting-drying cycle, the mass loss rate of sample is less than 20%. The durability of lignin treated silt is much better than that of lime treated silt. Hydrolysis, protonation, and electrostatic reaction between lignin and silt take place, and a more stable and compact soil structure is formed after the treatment. The road performance indicators of 12% lignin solidified silt after 15 days of curing are better than those of 8% lime treated silt, and the rebound deflection value is not more than 1mm. The penetration resistance with the variation of the curing period and depth can be employed to reflect the strength characteristics of treated silt subgrade. In addition, the environmental quality of the silt subgrade solidified by lignin meets the requirements of the secondary quality standard. The feasibility and environmental friendliness of the technology of silt subgrade solidified by lignin based industrial by-product is well verified.
[20]
ZHAO H, ZHOU K, ZHAO C, et al. A Long-term Investigation on Microstructure of Cement-stabilized Handan Clay[J]. European Journal of Environmental and Civil Engineering, 2016, 20(2): 199-214.
[21]
CHEW S H, KAMRUZZAMAN A H M, LEE F H. Physicochemical and Engineering Behavior of Cement Treated Clays[J]. Journal of Geotechnical and Geoenvironmental Engineering, 2004, 130(7): 696-706.
[22]
卢天伟. 不同环境下掺加纳米矿粉的淤泥固化土宏微观特性[D]. 重庆: 重庆交通大学, 2020.
(LU Tian-wei. Macro-and Micro-Characteristics of Sludge Solidified Soil Mixed with Nano-Mineral Powder in Different Environments[D]. Chongqing: Chongqing Jiaotong University, 2020.) (in Chinese)
[23]
丁建文, 洪振舜, 刘松玉. 疏浚淤泥流动固化处理与流动性试验研究[J]. 岩土力学, 2011, 32(增刊1):280-284.
(DING Jian-wen, HONG Zhen-shun, LIU Song-yu. Experimental Study on Flow Solidification Treatment and Fluidity of Dredged Sludge[J]. Rock and Soil Mechanics, 2011, 32(Supp.1): 280-284.) (in Chinese)
[24]
张亚灿, 赵仲辉, 胡孝彭, 等. 固化淤泥渗透性的微观分析[J]. 科学技术与工程, 2015, 15(7): 243-247.
(ZHANG Ya-can, ZHAO Zhong-hui, HU Xiao-peng, et al. Micro-analysis of Permeability Properties of Solidified Dredged Material[J]. Science Technology and Engineering, 2015, 15(7): 243-247.) (in Chinese)
[25]
郑晓培. 水泥土的渗透性及其计算模型[D]. 南京: 东南大学, 2018.
(ZHENG Xiao-pei. Permeability of Cement-Soil and Its Calculation Model[D]. Nanjing: Southeast University, 2018.) (in Chinese)
[26]
刘松玉, 曹菁菁, 蔡光华. 活性氧化镁碳化固化粉质黏土微观机制[J]. 岩土力学, 2018, 39(5):1543-1552,1563.
(LIU Song-yu, CAO Jing-jing, CAI Guang-hua. Microstructural Mechanism of Reactive Magnesia Carbonated and Stabilized Silty Clays[J]. Rock and Soil Mechanics, 2018, 39(5): 1543-1552, 1563.) (in Chinese)

基金

浙江省科技厅重点研发计划项目(2017C03008)
2020年度浙江省水利厅重点科技项目(RB2021)
2024年浙江省水利科技重大项目(RA2403)

编辑: 陈敏
PDF(8399 KB)

Accesses

Citation

Detail

段落导航
相关文章

/