长江科学院院报 ›› 2024, Vol. 41 ›› Issue (7): 163-167.DOI: 10.11988/ckyyb.20230240

• 水工结构与材料 • 上一篇    下一篇

炔属二醇表面活性剂在环氧树脂灌浆材料中的作用

魏涛1,2,3, 张健1,2,3, 张达1,2,3, 吴卫东4   

  1. 1.长江科学院 材料与结构研究所,武汉 430010;
    2.国家大坝安全工程技术研究中心,武汉 430010;
    3.水利部水工程安全与病害防治工程技术研究中心,武汉 430010;
    4.新疆生产建设兵团水利水电工程集团有限公司,乌鲁木齐 830000
  • 收稿日期:2023-03-10 修回日期:2023-06-19 出版日期:2024-07-01 发布日期:2024-07-01
  • 作者简介:魏 涛(1964-),男,湖北武汉人,正高级工程师,硕士,主要从事水工材料和化学灌浆研究。E-mail:weitao@mail.crsri.cn
  • 基金资助:
    国家自然科学基金项目(51378078,51609021);新疆生产建设兵团财政科技计划项目(2020AB010);中国华电金上公司科技项目(CHDKJ22-02-125)

Effect of Acetylene Glycol Surfactant in Epoxy Resin Grouting Material

WEI Tao1,2,3, ZHANG Jian1,2,3, ZHANG Da1,2,3, WU Wei-dong4   

  1. 1. Material Department, Changjiang River Scientific Research Institute, Wuhan 430010, China;
    2. National Research Center on Dam Safety Engineering Technology, Wuhan 430010, China;
    3. Engineering Technology Research Center of the Ministry of Water Resources on Water Engineering Safety and Disease Control Technologies, Wuhan 430010, China;
    4. Xinjiang Production and Construction Corps Water Conservancy and Hydropower Construction Engineering Group Co., Ltd., Urumqi 830000, China
  • Received:2023-03-10 Revised:2023-06-19 Published:2024-07-01 Online:2024-07-01

摘要: 通过在CW环氧树脂灌浆材料浆液中加入2种不同结构的非离子表面活性剂炔属二醇,制备了2种改性环氧树脂灌浆材料,并开展了黏度、表面张力、接触角、渗透性和浆材固化物力学强度的研究。结果表明:加入表面活性剂对浆液的黏度、浆材固结体抗压强度、抗拉强度无明显影响,但可以提高浆材的粘接强度和抗剪强度,降低浆液的表面张力和接触角,提高浆液在黏土中渗透性。其中,加入表面活性剂S1对浆液的粘接强度、拉伸剪切强度和在黏土中的浸润渗透高度提升更为显著,分别提高了23.6%、37.5%和109.4%。基于以上试验,初步探讨了表面活性剂提高浆液渗透性的机理。

关键词: 表面活性剂, 环氧树脂灌浆材料, 表面张力, 接触角, 渗透性

Abstract: Two types of modified epoxy resin grouting materials were formulated by incorporating different structured non-ionic surfactant alkynyl glycol into CW slurry. The viscosity, surface tension, contact angle, permeability, and mechanical strength of the cured slurry were investigated. Findings indicate that the addition of surface-active agents has no evident impact on viscosity, compressive strength, or tensile strength of the consolidated slurry. However,surface-active agents enhance the adhesive strength and shear strength, reduces surface tension and contact angle, and improves slurry permeability in clay. Addition of surfactant S1 significantly enhances adhesive strength, tensile shear strength, and permeability in clay by 23.6%, 37.5%, and 109.4%, respectively. Mechanisms underlying surfactant-induced improvements in slurry permeability are preliminarily discussed based on the tests.

Key words: surfactant, epoxy resin grouting material, surface tension, contact angle, permeability

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