天然有机物引起的超滤膜污染研究进展

丰桂珍; 杨银; 江立文

doi:10.11988/ckyyb.20181174

PDF(1089 KB)

长江科学院院报 ›› 2020, Vol. 37 ›› Issue (3) : 26-31. DOI: 10.11988/ckyyb.20181174

水资源与环境

天然有机物引起的超滤膜污染研究进展

丰桂珍, 杨银, 江立文

作者信息 +

Research Progress on the Fouling of Ultrafiltration Membrane by Natural Organic Matter

FENG Gui-zhen, YANG Yin, JIANG Li-wen

Author information +

文章历史 +

摘要

天然有机物(NOM)在多种地表环境介质中广泛存在。超滤(UF)膜有去除水体中胶体物质、部分细菌及病毒等优势,但NOM所带来的膜污染会限制UF技术广泛应用。在阐述天然有机物来源、特性及去除工艺的基础上,从亲疏水性能、分子量大小和表面荷电性能3方面,分析了NOM性质对超滤膜污染的影响。从优势污染物的确定、膜面有机污染物类型的解析、污染层形态特征的分析及微观相互作用力的表征4个层面,综述了天然有机物引起的超滤膜污染的研究现状,并对超滤膜污染机理研究的方向进行了展望。研究成果可为缓解NOM对UF膜的污染提供理论支撑。

Abstract

Natural organic matter (NOM) exists widely in multiple ground media. Ultrafiltration (UF) membrane has advantages of removing the colloidal substances, bacteria and viruses in water. Nevertheless, membrane fouling induced by NOM limits the broad application of UF technology. In this paper, the influence of NOM properties, inclusive of hydrophilic and hydrophobia performances, molecular weight, and surface charge performance, on membrane fouling is expounded based on introducing the sources, characteristics and removal techniques of NOM. Research progresses on the determining of dominant pollutant, the interpreting of organic pollutant types on membrane surface, the analysis of morphological characteristics of the fouling layer, and the characterization of microscopic interaction force are reviewed. Last but not the least, direction of research on the mechanism of UF membrane fouling is prospected. Research results can provide theoretical support for mitigation of NOM pollution on UF membranes.

导出引用

丰桂珍, 杨银, 江立文. 天然有机物引起的超滤膜污染研究进展[J]. 长江科学院院报. 2020, 37(3): 26-31 https://doi.org/10.11988/ckyyb.20181174

FENG Gui-zhen, YANG Yin, JIANG Li-wen. Research Progress on the Fouling of Ultrafiltration Membrane by Natural Organic Matter[J]. Journal of Changjiang River Scientific Research Institute. 2020, 37(3): 26-31 https://doi.org/10.11988/ckyyb.20181174

中图分类号： X52

参考文献

[1] TIAN J, WU C, YU H, et al. Applying Ultraviolet/Persulfate (UV/PS) Pre-oxidation for Controlling Ultrafiltration Membrane Fouling by Natural Organic Matter (NOM) in Surface Water. Water Research, 2018, 132:190-199.
[2] YU W, GRAHAM N J, FOWLER G D. Coagulation and Oxidation for Controlling Ultrafiltration Membrane Fouling in Drinking Water Treatment: Application of Ozone at Low Dose in Submerged Membrane Tank. Water Research, 2016, 95:1-10.
[3] MOPPER K, STUBBINS A, RITCHIE J D, et al. Advanced Instrumental Approaches for Characterization of Marine Dissolved Organic Matter: Extraction Techniques, Mass Spectrometry, and Nuclear Magnetic Resonance Spectroscopy. Chemical Reviews, 2007, 107(2): 419-442.
[4] AIKEN G R, HSU-KIM H, RYAN J N. Influence of Dissolved Organic Matter on the Environmental Fate of Metals, Nanoparticles, and Colloids. Environmental Science & Technology, 2011, 45(8): 3196-3201.
[5] 王龙飞. 天然有机质与金属离子/纳米颗粒的相互作用及其对膜污染过程的影响.合肥: 中国科学技术大学, 2016.
[6] MALCOLM R L. The Uniqueness of Humic Substances in Each of Soil, Stream and Marine Environments. Analytica Chimica Acta, 1990, 232(1): 19-30.
[7] MCDONALD S, BISHOP A G, PRENZLER P D, et al. Analytical Chemistry of Freshwater Humic Substances. Analytica Chimica Acta, 2004, 527(2): 105-124.
[8] MATILAINEN A,GJESSING E T,LAHTINEN T,et al. An Overview of the Methods Used in the Characterisation of Natural Organic Matter(NOM) in Relation to Drinking Water Treatment.Chemosphere,2011,83(11):1431-1442.
[9] PHILIPPE A, SCHAUMANN G E. Interactions of Dissolved Organic Matter with Natural and Engineered Inorganic Colloids: A Review . Environmental Science & Technology, 2014, 48(16): 8946-8962.
[10] XING J, WANG H, CHENG X, et al. Application of Low-dosage UV/chlorine Pre-oxidation for Mitigating Ultrafiltration (UF) Membrane Fouling in Natural Surface Water Treatment. Chemical Engineering Journal, 2018, 344:62-70.
[11] ZULARISAM A W, ISMAIL A F, SALIM R. Behaviours of Natural Organic Matter in Membrane Filtration for Surface Water Treatment—A Review . Desalination, 2006, 194(1): 211-231.
[12] SHIMIZU Y, ATEIA M, YOSHIMURA C. Natural Organic Matter Undergoes Different Molecular Sieving by Adsorption on Activated Carbon and Carbon Nanotubes. Chemosphere, 2018, 203: 345-352.
[13] GAO F, WANG J, ZHANG H, et al. Interaction Energy and Competitive Adsorption Evaluation of Different NOM Fractions on Aged Membrane Surfaces. Journal of Membrane Science, 2017, 542: 195-207.
[14] SILLANP M, NCIBI M C, MATILAINEN A, et al. Removal of Natural Organic Matter in Drinking Water Treatment by Coagulation: A Comprehensive Review. Chemosphere, 2018, 190: 54-71.
[15] CAHYONUGROHO O H,HIDAYAH E N. Characterization of Natural Organic Matter by FeCl₃ Coagulation.Journal of Physics Conference Series,2018,953(1):012217.
[16] 杨海洋. 混凝/超滤处理微污染地表水及滤饼调控去除污染物研究.哈尔滨: 哈尔滨工业大学, 2017.
[17] WEI D, TAO Y, ZHANG Z, et al. Effect of Pre-ozonation on Mitigation of Ceramic UF Membrane Fouling Caused by Algal Extracellular Organic Matters . Chemical Engineering Journal, 2016, 294: 157-166.
[18] LI K, QU F, LIANG H, et al. Performance of Mesoporous Adsorbent Resin and Powdered Activated Carbon in Mitigating Ultrafiltration Membrane Fouling Caused by Algal Extracellular Organic Matter. Desalination, 2014, 336(1): 129-137.
[19] 吴璀蔚.UV/PDS工艺的NOM去除效能及对超滤膜污染的控制研究. 哈尔滨:哈尔滨工业大学,2017.
[20] WANG H, DING A, GAN Z, et al. Fluorescent Natural Organic Matter Responsible for Ultrafiltration Membrane Fouling: Fate, Contributions and Fouling Mechanisms. Chemosphere, 2017, 182:183-193.
[21] WANG Z, TEYCHENE B, CHALEW T E A, et al. Aluminum-humic Colloid Formation during Pre-coagulation for Membrane Water Treatment: Mechanisms and Impacts. Water Research, 2014, 61(18): 171-180.
[22] 杨海燕, 王灿, 赵焱,等. 东江水膜污染物质的确定及污染机理研究. 哈尔滨工业大学学报, 2017, 49(8): 8-14.
[23] QU F, LIANG H, WANG Z, et al. Ultrafiltration Membrane Fouling by Extracellular Organic Matters (EOM) of Microcystisaeruginosa in Stationary Phase: Influences of Interfacial Characteristics of Foulants and Fouling Mechanisms. Water Research, 2012, 46(5): 1490-1500.
[24] 董秉直, 高昊旸, 胡孟柳. 臭氧-粉末炭联用作为预处理缓解膜污染的效果与机制. 环境科学, 2018, 39(6): 2732-2739.
[25] KAI L, HUANG T, QU F, et al. Performance of Adsorption Pretreatment in Mitigating Humic Acid Fouling of Ultrafiltration Membrane under Environmentally Relevant Ionic Conditions. Desalination, 2016, 377:91-98.
[26] QU F, LIANG H, HE J, et al. Characterization of Dissolved Extracellular Organic Matter (dEOM) and Bound Extracellular Organic Matter (bEOM) of Microcystisaeruginosa and Their Impacts on UF Membrane Fouling. Water Research, 2012, 46(9): 2881-2890.
[27] 邓东旭, 王磊, 李兴飞,等. 超滤过程中蛋白质带电性对水合作用的影响机制. 哈尔滨工业大学学报, 2017, 49(8): 78-82.
[28] SHAO S, LIANG H, QU F, et al. Combined Influence by Humic Acid (HA) and Powdered Activated Carbon (PAC) Particles on Ultrafiltration Membrane Fouling. Journal of Membrane Science, 2016, 500: 99-105.
[29] RUI M, LEI W, LV Y, et al. Identifying Polyvinylidene Fluoride Ultrafiltration Membrane Fouling Behavior of Different Effluent Organic Matter Fractions Using Colloidal Probes. Water Research, 2014, 55: 313-322.
[30] XIAO F, XIAO P, ZHANG W J, et al. Identification of Key Factors Affecting the Organic Fouling on Low-pressure Ultrafiltration Membranes. Journal of Membrane Science, 2013, 447(1): 144-152.

[31] GAMAGE N P, CHELLAM S. Mechanisms of Physically Irreversible Fouling during Surface Water Microfiltration and Mitigation by Aluminum Electroflotation Pretreatment . Environmental Science & Technology, 2014, 48(2): 1148-1157.
[32] SHEN Y, ZHAO W, XIAO K, et al. A Systematic Insight into Fouling Propensity of Soluble Microbial Products in Membrane Bioreactors Based on Hydrophobic Interaction and Size Exclusion. Journal of Membrane Science, 2010, 346(1): 187-193.
[33] MIAO R, WANG L, MI N, et al. Enhancement and Mitigation Mechanisms of Protein Fouling of Ultrafiltration Membranes under Different Ionic Strengths. Environmental Science & Technology, 2015, 49(11): 6574-6580.
[34] 孙春意. xDLVO理论定量解析纳米SiO₂和天然有机物超滤膜污染机理. 济南:山东大学, 2018.