长江科学院院报 ›› 2016, Vol. 33 ›› Issue (7): 18-22.DOI: 10.11988/ckyyb.20150235

• 水资源与环境 • 上一篇    下一篇

凹凸棒石纳米铁复合材料的制备及应用探讨

冯雪a, 董磊b,c, 李青云b,c, 林莉b,c   

  1. 长江科学院 a.人事处;b.流域水环境研究所;c.流域水资源与生态环境科学湖北省重点实验室,武汉 430010
  • 收稿日期:2015-03-31 出版日期:2016-07-01 发布日期:2016-07-11
  • 作者简介:冯 雪(1986-),女,四川成都人,工程师,硕士,主要从事水环境治理方面的研究,(电话)027-82820016(电子信箱)fengxue_55@163.com。
  • 基金资助:
    国家自然科学基金项目(41302204);中央级公益性科研院所基本科研业务费项目(CKSF2014029/SH)

Preparation and Application of Palygorskite/Nano-iron Composite

FENG Xue1, DONG Lei2,3, LI Qing-yun2,3, LIN Li2,3   

  1. 1.Human Resources Management Department, Yangtze River Scientific Research Institute, Wuhan 430010, China;
    2.Basin Water Environmental Research Department, Yangtze River Scientific Research Institute, Wuhan 430010, China;
    3.Key Lab of Basin Water Resource and Eco-environmental Science in Hubei Province,Yangtze River Scientific Research Institute,Wuhan 430010,China
  • Received:2015-03-31 Online:2016-07-01 Published:2016-07-11

摘要: 通过对凹凸棒石进行湿法提纯和酸处理改性提高凹凸棒石的纯度、比表面积和吸附性能;将提纯改性后的凹凸棒石作为载体,以硼氢化钾作为还原剂,在氩气保护下采用离子交换法制备凹凸棒石纳米铁复合材料,解决纳米铁稳定性差、容易凝聚成团的问题,从而增大纳米铁与污染物反应的有效面积。与纳米铁相比,凹凸棒石纳米铁复合材料较稳定,易于保存。以地下水中常见的硝酸盐为目标污染物,探讨了将凹凸棒石纳米铁复合材料应用到可渗透反应墙技术、抽出处理技术及注入修复技术中的方法。应用研究成果表明,经上述技术处理后,地下水硝酸盐浓度可得到有效去除。

关键词: 凹凸棒石, 湿法提纯, 酸处理, 纳米铁, 硝酸盐, 地下水

Abstract: The purity, specific surface area and adsorption properties of palygorskite were improved through wet purification and acid modification. The modified palygorskite was used as a carrier and KBH4 as a reducing agent to prepare palygorskite/nano-iron composite material using ion exchange method under the protection of argon gas. Hence, the stability of nano-iron could be enhanced, iron-nano particles were prevented from condensing into groups, and the effective area of the nano-iron reacting with pollutants could be increased. Compared with nano-iron, palygorskite/nano-iron composite is more stable and easier to store. Furthermore, with nitrate as target contaminant in groundwater for example, the usage of palygorskite/nano-iron composite in permeable reactive barrier technology, extraction processing technology and injection processing technology in removing nitrate was discussed. Treated by these techniques, the nitrate concentration in groundwater can be effectively degraded.

Key words: palygorskite, wet purification, acid processing, nano-iron, nitrates, groundwater

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