Dolomite was modified through calcination mixed with muck. The effects of calcined muck-dolomite on the strength and expansion properties of cement mortar were investigated. The hydration products of cement containing calcined muck-dolomite were examined by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectrometer (EDS). Results show that β-C2S and C12A7 were generated in calcined muck-dolomite, and the content of β-C2S and C12A7 increased with the rising of calcination temperature. The incorporation of calcined muck-dolomite improves the strengths of blended cement mortar effectively at later age. Cement mortar containing 10% calcined muck-dolomite even gain a higher strength at 90 d than pure cement mortars. In addition, the hydration of MgO in calcined muck-dolomite gave rise to Mg(OH)2, resulting in the expansion of cement mortars, and the expansion rate augmented with the increase of dosage of calcined muck-dolomite. The research finding is of referential value for promoting the application of dolomite in cement concrete and for reducing the pollution of construction wastes.
CHEN Deng
,
SONG Xu-yan
,
HE Zhi-hai
. Effects of Calcined Muck-Dolomite on Strengths and Expansion Properties of Cement Mortar[J]. Journal of Changjiang River Scientific Research Institute, 2021
, 38(1)
: 146
-150
.
DOI: 10.11988/ckyyb.20191066
[1] STUKOVNIK P, BOSILJKOV V B, MARINSEK M. Detailed Investigation of ACR in Concrete with Silica-free Dolomite Aggregate[J]. Construction and Building Materials, 2019, 216:325-336.
[2] KRISHNAN S, BISHNOI S. Understanding the Hydration of Dolomite in Cementitious Systems with Reactive Aluminosilicates Such as Calcined Clay[J]. Cement and Concrete Research, 2018, 108:116-128.
[3] 彭 园, 高育欣, 赵日煦, 等. 白云石粉用作混凝土掺合料的试验研究[J]. 混凝土与水泥制品, 2014(6):13-16.
[4] GARCIA E, ALFONSO P, LABRADOR M, et al. Dedolomitization in Different Alkaline Media: Application to Portland Cement Paste[J]. Cement and Concrete Research, 2003, 33 (9):1443-1448.
[5] DENG M, TANG M S. Mechanism of Dedolomitization and Expansion of Dolomitic Rocks[J]. 1993, 23(6):1397-1408.
[6] XU L L, DENG M. Dolomite Used as Raw Material to Produce MgO-based Expansive Agent[J]. Cement and Concrete Research, 2005, 35:1480-1485.
[7] MO L W, DENG M, TANG M S, et al. MgO Expansive Cement and Concrete in China: Past, Present and Future[J]. Cement and Concrete Research, 2014, 57:1-12.
[8] CAO F Z, MIAO M, YAN P Y. Effects of Reactivity of MgO Expansive Agent on Its Performance in Cement-based Materials and an Improvement of the Evaluating Method of MEA Reactivity[J]. Construction and Building Materials, 2018, 187:257-266.
[9] XIAO J Z, MA Z M, DING T. Reclamation Chain of Waste Concrete: A Case Study of Shanghai[J]. Waste Management, 2015, 48:334-343.
[10]YANG J, DU Q, BAO Y. Concrete with Recycled Concrete Aggregate and Crushed Clay Bricks[J]. Construction and Building Materials, 2011, 25(4):1935-1945.
[11]陈守开, 张政男, 郑永杰, 等. 再生骨料透水混凝土耐撞磨性试验研究[J]. 长江科学院院报, 2020, 37(7):153-159.
[12]陶 喆, 王瑞骏, 李 阳, 等. 受硫酸盐侵蚀的再生混凝土耐久性研究[J]. 长江科学院院报, 2019, 36(9):136-141.
[13]杨南如. 水热合成β-C2S的研究进展[J]. 建筑材料学报, 2011, 14(2):145-154.
[14]严 生, 蔡安兰, 周际东. C2S-C12A7-CaSO4· 2H2O-H2O系统水化机理[J]. 硅酸盐学报, 2004, 32(4):520-523.
[15]MO L W, DENG M, TANG M S. Effects of Calcination Condition on Expansion Property of MgO-type Expansive Agent Used in Cement-based Materials[J]. Cement and Concrete Research, 2010, 40:437-446.