岩土工程

热解过程中油页岩弹性模量变化规律

  • 徐兴倩 ,
  • 刘剑 ,
  • 屈新 ,
  • 张新启 ,
  • 窦思军
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  • 1.云南农业大学 水利学院,昆明 650201;
    2.山西能源学院 地质测绘工程系,山西 晋中 030600;
    3.河北工程大学 地球科学与工程学院,河北 邯郸 056038;
    4.太原理工大学 原位改性采矿教育部重点实验室,太原 030024;
    5.安阳工学院 土木与建筑工程学院,河南 安阳 455000
徐兴倩(1985-),男,云南宣威人,讲师,博士,从事岩土工程方面的研究。E-mail:xuxingqian_123@163.com

收稿日期: 2019-10-15

  修回日期: 2020-02-29

  网络出版日期: 2021-03-17

基金资助

山西省应用基础研究项目(201801D221329);河北省自然科学基金项目(E2019402361,E2020402075);国家自然科学基金项目(41867040);河北省博士后科研项目择优资助项目(B2020003010);河北工程大学博士基金项目(BSJJ1930)

Variation Rules of Elastic Modulus of Oil Shale during Pyrolysis

  • XU Xing-qian ,
  • LIU Jian ,
  • QU Xin ,
  • ZHANG Xin-qi ,
  • DOU Si-jun
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  • 1. College of Water Conservancy, Yunnan Agricultural University, Kunming 650201, China;
    2. Department of Geological Survey Engineering, Shanxi Institute of Energy, Jinzhong 030600, China;
    3. School of Earth Science and Engineering, Hebei University of Engineering, Handan 056038, China;
    4. Key Laboratory of In-situ Modification of Deposit Properties for Improving Mining of Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, China;
    5. School of Civil and Architecture Engineering, Anyang Institute of Technology, Anyang 455000, China

Received date: 2019-10-15

  Revised date: 2020-02-29

  Online published: 2021-03-17

摘要

为预测原位热解工艺带来的采区水文地质环境变化,通过控制热解温度和时间以研究不同热解程度油页岩的弹性模量变化规律。分析了油页岩弹性模量变化机理,结合油页岩热解反应速率方程,提出了热解过程中油页岩的弹性模量定量计算模型。将弹性模量试验值与计算值进行了对比分析,结果表明:计算值与试验值较为吻合,两者误差较小,提出的定量计算模型能较准确地估算热解过程中油页岩弹性模量。该模型对油页岩原位热解采区孔隙率、渗透率、地下水污染物运移模拟研究具有一定借鉴意义。

本文引用格式

徐兴倩 , 刘剑 , 屈新 , 张新启 , 窦思军 . 热解过程中油页岩弹性模量变化规律[J]. 长江科学院院报, 2021 , 38(3) : 110 -114 . DOI: 10.11988/ckyyb.201912482021

Abstract

In the aim of predicting the hydrogeological environment changes in mining area caused by in-situ pyrolysis process, we examined the variation rules of elastic modulus of oil shale by controlling the pyrolysis temperature and time. We established a quantitative model of the elastic modulus of oil shale during pyrolysis based on the pyrolysis reaction rate equation. We further compared the test values with calculation values, and results suggest that the calculated elastic modulus values from the quantitative model are in good agreement with the experimental data, with a relatively small error. The proposed quantitative model accurately estimates the elastic modulus of oil shale during pyrolysis, thus is of referential value for the simulation of porosity, permeability, and groundwater pollutant transport in oil shale in-situ pyrolysis mining area.

参考文献

[1] 刘 剑,梁卫国.页岩油气及煤层气开采技术与环境现状及存在问题[J].科学技术与工程,2017,17(30):121-134.
[2] 孙可明,赵阳升,杨 栋.非均质热弹塑性损伤模型及其在油页岩地下开发热破裂分析中的应用[J].岩石力学与工程学报,2008,27(1):42-52.
[3] ESEME E, KROOSS B M, LITTKE R. Evolution of Petrophysical Properties of Oil Shales during High-temperature Compaction Tests: Implications for Petroleum Expulsion[J]. Marine and Petroleum Geology, 2012, 31(1): 110-124.
[4] 姜 雪.油页岩原位开采对地下水环境的影响研究[D]. 长春:吉林大学,2014.
[5] 赵 静.高温及三维应力下油页岩细观特征及力学特性试验研究[D].太原:太原理工大学,2014.
[6] RAO K S, KUMAR A. Geological and Engineering Behavior of Oil Shales[C]//Proceedings of the International Conference on Engineering Geology in New Millennium. New Delhi, October 27-29, 2015: 279-285.
[7] KUMAR A, RAO K S. Engineering Behavior of Oil Shale at Elevated Temperature and Confining Pressure[C]//Proceedings of the 5th Young Indian Geotechnical Engineers Conference. Vadodara, India, March 14-15, 2015: 102-109.
[8] BAI F, SUN Y, LIU Y, et al. Evaluation of the Porous Structure of Huadian Oil Shale during Pyrolysis Using Multiple Approaches[J]. Fuel, 2017, 187(1): 1-8.
[9] GENG Y, LIANG W, LIU J, et al. Evolution of Pore and Fracture Structure of Oil Shale under High Temperature and High Pressure[J]. Energy & Fuels, 2017, 31(10):10404-10413.
[10] 刘洪鹏,张少冲,王 擎.油页岩半焦燃烧过程中官能团演化特性研究[J].科学技术与工程,2017,17(7): 35-41.
[11] 刘洪鹏,郭 超,巩时尚,等.龙口油页岩半焦燃烧破碎特性研究[J].科学技术与工程,2017,17(7): 168-172.
[12] 耿毅德.油页岩地下原位压裂-热解物理力学特性试验研究[D].太原:太原理工大学,2018.
[13] 郭树才,耿丽文.几种油页岩热重法热解动力学的研究[J].燃料化学学报,1986,14(3):211-217.
[14] 于忻邑.吉木萨尔油页岩热解及其灰渣利用[D]. 乌鲁木齐:新疆大学,2015.
[15] 郭晋宇,刘 剑,耿毅德.热解过程中油页岩孔隙率变化规律[J].科学技术与工程,2019,19(35):107-112.
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